Chemical Sciences: A Manual for CSIR-UGC National Eligibility Test for Lectureship and JRF/Binding energy

Binding energy is the mechanical energy required to disassemble a whole into separate parts. A bound system has a lower potential energy than its constituent parts; this is what keeps the system together. The usual convention is that this corresponds to a positive binding energy.

In general, binding energy represents the mechanical work which must be done in acting against the forces which hold an object together, while disassembling the object into component parts separated by such sufficient distance that further separation requires negligible additional work.

Electron binding energy is a measure of the energy required to free electrons from their atomic orbits.

Nuclear binding energy is derived from the strong nuclear force and is the energy required to disassemble a nucleus into free unbound neutrons and protons. At the atomic level, the binding energy of the atom is derived from electromagnetic interaction and is the energy required to disassemble an atom into free electrons and a nucleus. In astrophysics, gravitational binding energy of a celestial body is the energy required to disassemble it into space debris (dust and gas). This quantity is not to be confused with the gravitational potential energy, which is the energy required to separate two bodies, such as a celestial body and a satellite, to infinite distance, keeping each intact (the latter energy is lower).

Mass defect
Because a bound system is at a lower energy level than its unbound constituents, its mass must be less than the total mass of its unbound constituents. For systems with low binding energies, this "lost" mass after binding, may be fractionally small. For systems with high binding energies, however, the missing mass may be an easily measurable fraction.

Since all forms of energy in a system (which has no net momentum) have mass, the question of where the missing mass of the binding energy goes is of interest. The answer is that this mass does not "disappear" into energy (a common misconception); rather, transformed to heat or light, this mass may move away to another location. The "mass defect" from binding energy is therefore only mass which has moved. However, it remains mass, because mass is conserved in systems for any given single observer, so long as the system remains closed. Thus, if binding energy mass is transformed into heat, the system must be cooled (the heat removed) before the mass-deficit appears in the cooled system. In that case, the removed heat (which has mass itself when measured in the original inertial frame) represents exactly the mass "deficit".

For example, when two large objects (such as the earth and a meteor) are attracted by a gravitational field and collide, the energy for the heat of impact is extracted from the gravitational field of the objects. However, the system does not lose mass (which represents its binding energy) until this heat is radiated into space, and this space is no longer counted as part of the original system (equivalent to opening the original system).

Closely analogous considerations apply in chemical and nuclear considerations. However, in nuclear reactions, the fraction of mass which may be removed as light or heat, and which then appears as binding energy, is often a much larger fraction of the system mass. This is because nuclear forces are comparatively stronger than other forces.

In nuclear reactions, the "light" which must be radiated to remove binding energy may be in the form of direct gamma radiation. Again, however, no mass-deficit can in theory appear until this radiation has been emitted and is no longer part of the system.

The energy given off during either nuclear fusion or nuclear fission is the difference between the binding energies of the fuel and the fusion or fission products. In practice, this energy may also be calculated from the substantial mass differences between the fuel and products, once evolved heat and radiation have been removed.

Atomic binding energy
The binding energy for a single atom is given by

$$\Delta E = \Delta m \cdot c^2 = (m_s - m_b) \cdot c^2 = (Z \cdot m_p + N \cdot m_n - m_b) \cdot c^2$$

where


 * c is the speed of light;
 * ms is the mass of the separated nucleons;
 * mb is the mass of the bound nucleus;
 * Z is the atomic number of the bound nucleus;
 * mp is the mass of one proton;
 * N is the number of neutrons;
 * mn is the mass of one neutron.

Specific quantitative example: a deuteron
A deuteron is the nucleus of a deuterium atom, and consists of one proton and one neutron. The experimentally-measured masses of the constituents as free particles are


 * mproton = 1.007825 u;
 * mneutron= 1.008665 u;
 * mproton + mneutron = 1.007825 + 1.008665 = 2.01649 u.

The mass of the deuteron (also an experimentally measured quantity) is


 * Atomic mass 2H = 2.014102 u.

The mass difference = 2.01649 - 2.014102 = 0.002388 u. Since the conversion between rest mass and energy is 931.494MeV/u, a deuteron's binding energy is calculated to be


 * 0.002388 u × 931.494 MeV/u = 2.224 MeV.

Thus, expressed in another way, the binding energy is [0.002388/2.01649] x 100% = about 0.1184% of the total energy corresponding to the mass. This corresponds to 1.07 x $$10^{14}$$ J/kg = 107 TJ/kg.

Nuclear binding energy curve
In the periodic table of elements, the series of light elements from hydrogen up to sodium is observed to exhibit generally increasing binding energy per nucleon as the atomic mass increases. This increase is generated by increasing forces per nucleon in the nucleus, as each additional nucleon is attracted by all of the other nucleons, and thus more tightly bound to the whole.

The region of increasing binding energy is followed by a region of relative stability (saturation) in the sequence from magnesium through xenon. In this region, the nucleus has become large enough that nuclear forces no longer completely extend efficiently across its width. Attractive nuclear forces in this region, as atomic mass increases, are nearly balanced by repellant electromagnetic forces between protons, as atomic number increases.

Finally, in elements heavier than xenon, there is a decrease in binding energy per nucleon as atomic number increases. In this region of nuclear size, electromagnetic repulsive forces are beginning to gain against the strong nuclear force.

At the peak of binding energy, nickel-62 is the most tightly-bound nucleus, followed by iron-58 and iron-56. (This is the basic reason why iron and nickel are very common metals in planetary cores, since they are produced profusely as end products in supernovae).

The existence of a maximum in binding energy in medium-sized nuclei is a consequence of the trade-off in the effects of two opposing forces which have different range characteristics. The attractive nuclear force (strong nuclear force), which binds protons and neutrons equally to each other, has a limited range due to a rapid exponential decrease in this force with distance. However, the repelling electromagnetic force, which acts between protons to force nuclei apart, falls off with distance much more slowly (as the inverse square of distance). For nuclei larger than about four nucleons in diameter, the additional repelling force of additional protons more than offsets any binding energy which results between further added nucleons as a result of additional strong force interactions; such nuclei become less and less tightly bound as their size increases, though most of them are still stable. Finally, nuclei containing more than 209 nucleons (larger than about 6 nucleons in diameter) are all too large to be stable, and are subject to spontaneous decay to smaller nuclei.

Nuclear fusion produces energy by combining the very lightest elements into more tightly-bound elements (such as hydrogen into helium), and nuclear fission produces energy by splitting the heaviest elements (such as uranium and plutonium) into more tightly-bound elements (such as barium and krypton). Both processes produce energy, because middle-sized nuclei are the most tightly bound of all.

Semiempirical formula
For a nucleus with A nucleons including Z protons, a semiempirical formula for the binding energy per nucleon is

$$E/A=a-b/\sqrt[3]{A}-c(Z/\sqrt[3]{A^2})^2-d(N-Z)^2/\sqrt[3]{A^{3+3}}\pm e/\sqrt[4]{A^{3+4}}$$

where the binding energy is in MeV for the following numerical values of the constants: $$a=14.0$$; $$b=13.0$$; $$c=0.585$$; $$d=19.3$$; $$e=33$$.

The first term $$a\,$$ is called the saturation contribution and ensures that the B.E. per nucleon is the same for all nuclei to a first approximation.

The term $$-b/A^{1/3}\,$$ is a surface tension effect and is proportional to the number of nucleons that are situated on the nuclear surface. It is largest for light nuclei.

The term $$-cZ^2/A^{4/3}\,$$ is the Coulomb electrostatic repulsion. This becomes more important as $$Z$$ increases.

The symmetry correction term $$-d(N-Z)^2/A^2\,$$ takes into account the fact that in the absence of other effects the most stable arrangement has equal numbers of protons and neutrons. This is because the n-p interaction in a nucleus is stronger than either the n-n or p-p interaction.

The pairing term $$\pm e/A^{7/4}$$ is purely empirical. It is + for even-even nuclei and − for odd-odd nuclei.

The following table gives the binding energy per nucleon in MeV for selected isotopes.

Measuring the binding energy
As seen above in the example of deuterium, nuclear binding energies are large enough that they may be easily measured as fractional mass deficits, according to the equivalence of mass and energy. The atomic binding energy is simply the amount of energy (and mass) released, when a collection of free nucleons are joined together to form a nucleus. All nuclei which last long enough to be weighed, are measurably lighter than a corresponding collection of free protons and neutrons.

Nuclear binding energy can be easily computed from the easily measurable difference in mass of a nucleus, and the sum of the masses of the number of free neutrons and protons that make up the nucleus. Once this mass difference, called the mass defect or mass deficiency, is known, Einstein's mass-energy equivalence formula E = mc² can be used to compute the binding energy of any nucleus. (As a historical note, early nuclear physicists used to refer to computing this value as a "packing fraction" calculation.)

For example, the atomic mass unit (1.000000 u) is defined to be 1/12 of the mass of a 12C atom—but the atomic mass of a 1H atom (which is a proton plus electron) is 1.007825 u, so each nucleon in 12C has lost, on average, about 0.8% percent of its mass in the form of binding energy.